Molybdenum Site Structure of MOSC Family Proteins

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Molybdenum Site Structure of MOSC Family Proteins

Mo K-edge X-ray absorption spectroscopy has been used to probe as-isolated structures of the MOSC family proteins pmARC-1 and HMCS-CT. The Mo K-edge near-edge spectrum of HMCS-CT is shifted ~2.5 eV to lower energy compared to the pmARC-1 spectrum, which indicates that as-isolated HMCS-CT is in a more reduced state than pmARC-1. Extended X-ray absorption fine structure analysis indicates signifi...

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ژورنال

عنوان ژورنال: Inorganic Chemistry

سال: 2014

ISSN: 0020-1669,1520-510X

DOI: 10.1021/ic5015863